Hi,
Regards a v-2-p of the vcenter server take a look at http://communities.vmware.com/thread/342863?start=0&tstart=0
Really 2 steps with above i) migrate DB to your new destination and ii) Then point the clean installation of vcenter on your physical vcenter server to your new DB location
In terms of the migration of the SRM database along with the vcenter piece take a look at : http://kb.vmware.com/selfservice/microsites/search.do?language=en_US&cmd=displayKC&externalId=2000539